The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 09, 2021

Filed:

Apr. 13, 2020
Applicants:

Dow Global Technologies Llc, Midland, MI (US);

The Regents of the University of Michigan, Ann Arbor, MI (US);

Inventors:

Melanie S. Sanford, Ann Arbor, MI (US);

Douglas Bland, Midland, MI (US);

Patrick S. Hanley, Midland, MI (US);

Megan A. Cismesia, Midland, MI (US);

Sydonie D. Schimler, Ann Arbor, MI (US);

Assignees:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 17/02 (2006.01); C07D 453/02 (2006.01); C07D 311/16 (2006.01); C07C 17/093 (2006.01); C07D 209/08 (2006.01); C07D 213/79 (2006.01); C07D 213/61 (2006.01); C07C 231/12 (2006.01); C07C 41/22 (2006.01); C07C 45/63 (2006.01); C07D 213/57 (2006.01); C07C 201/12 (2006.01); C07C 67/307 (2006.01); C07D 213/75 (2006.01); C07J 21/00 (2006.01); C07D 279/16 (2006.01); C07C 253/30 (2006.01); C07D 209/88 (2006.01); C07D 215/18 (2006.01); C07C 25/13 (2006.01); C07C 317/14 (2006.01);
U.S. Cl.
CPC ...
C07C 17/02 (2013.01); C07C 17/093 (2013.01); C07C 25/13 (2013.01); C07C 41/22 (2013.01); C07C 45/63 (2013.01); C07C 67/307 (2013.01); C07C 201/12 (2013.01); C07C 231/12 (2013.01); C07C 253/30 (2013.01); C07C 317/14 (2013.01); C07D 209/08 (2013.01); C07D 209/88 (2013.01); C07D 213/57 (2013.01); C07D 213/61 (2013.01); C07D 213/75 (2013.01); C07D 213/79 (2013.01); C07D 215/18 (2013.01); C07D 279/16 (2013.01); C07D 311/16 (2013.01); C07D 453/02 (2013.01); C07J 21/008 (2013.01);
Abstract

Disclosed is a fluorination method comprising providing an aryl fluorosulfonate and a fluorinating reagent to a reaction mixture; and reacting the aryl fluorosulfonate and the fluorinating reagent to provide a fluorinated aryl species. Also disclosed is a fluorination method comprising providing, a salt comprising a cation and an aryloxylate, and SOFto a reaction mixture; reacting the SOFand the ammonium salt to provide a fluorinated aryl species. Further disclosed a fluorination method comprising providing a compound having the structure Ar—OH to a reaction mixture; where Ar is an aryl or heteroaryl; providing SOFto the reaction mixture; providing a fluorinating reagent to the reaction mixture; reacting the SOF, the fluorinating reagent and the compound having the structure Ar—OH to provide a fluorinated aryl species having the structure Ar—F.


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