The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 15, 2020

Filed:

Jul. 11, 2018
Applicant:

Northwestern University, Evanston, IL (US);

Inventors:

Zhichang Liu, Evanston, IL (US);

Junling Sun, Albany, NY (US);

James Fraser Stoddart, Evanston, IL (US);

Assignee:

Northwestern University, Evanston, IL (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
H01B 1/12 (2006.01); C07D 401/14 (2006.01); C07D 519/00 (2006.01); C07D 471/06 (2006.01); C30B 29/54 (2006.01);
U.S. Cl.
CPC ...
H01B 1/122 (2013.01); C07D 401/14 (2013.01); C07D 471/06 (2013.01); C07D 519/00 (2013.01); C30B 29/54 (2013.01);
Abstract

Provided herein are mechanically interlocked air-stable persistent organic radicals. The radical compositions may access a multiplicity of radical, cationic redox states as well as a fully cationic redox state. A composition comprises a first ring mechanically interlocked with a second ring or a salt thereof, wherein the first ring comprises a 4,4'-bipyridinium subunit or a derivative thereof and a diazapyrenium subunit or a derivative thereof and the second ring comprises a 4,4′-bipyridinium subunit or a derivative thereof. In some embodiments, the second ring further comprises a diazapyrenium subunit or a derivative thereof. Methods of preparing the compositions are also provided.


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