The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 15, 2020

Filed:

Dec. 10, 2019
Applicant:

Basf Corporation, Florham Park, NJ (US);

Inventor:

Dieter G. Von Deak, Hazlet, NJ (US);

Assignee:

BASF CORPORATION, Florham Park, NJ (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 23/52 (2006.01); C07C 67/055 (2006.01); B01J 31/02 (2006.01); B01J 31/04 (2006.01); B01J 35/02 (2006.01); B01J 35/10 (2006.01); B01J 37/02 (2006.01); B01J 37/16 (2006.01); B01J 35/00 (2006.01);
U.S. Cl.
CPC ...
B01J 23/52 (2013.01); B01J 31/02 (2013.01); B01J 31/0205 (2013.01); B01J 31/04 (2013.01); B01J 35/023 (2013.01); B01J 35/1019 (2013.01); B01J 35/1023 (2013.01); B01J 35/1028 (2013.01); B01J 37/02 (2013.01); B01J 37/0201 (2013.01); B01J 37/024 (2013.01); B01J 37/16 (2013.01); C07C 67/055 (2013.01); B01J 35/0026 (2013.01); B01J 35/026 (2013.01); B01J 2523/00 (2013.01);
Abstract

A catalyst includes a support, where the support includes an external surface, about 60 wt % to about 99 wt % silica, and about 1.0 wt % to about 5.0 wt % alumina. A catalytic layer is disposed within the support adjacent to the external surface, where the catalytic layer further includes Pd, Au, and potassium acetate (KOAc). In the catalyst, (a) the KOAc is from about 60 kg/mto about 150 kg/mof the catalyst; or (b) the catalytic layer has an average thickness from about 50 μm to about 150 μm; or (c) both (a) and (b). The catalyst also possesses a Brunauer-Emmett-Teller surface area of about 130 m/g to about 300 m/g and a geometric surface area per packed bed volume from about 550 m/mto about 1500 m/m. The catalyst is highly active for the synthesis of vinyl acetate monomer and exhibits a high selectivity for vinyl acetate monomer.


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