The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Patent No.:

US 10854937 B1

PDF
Full Text
Expired
Date of Patent:
Dec. 01, 2020

Filed:

Jan. 16, 2019
Applicant:

The Trustees of Boston College, Chestnut Hill, MA (US);

Inventors:

Dunwei Wang, Newton, MA (US);

Qingmei Cheng, Brighton, MA (US);

Assignee:

The Trustees of Boston College, Chestnut Hill, MA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
H01M 14/00 (2006.01); H01M 8/18 (2006.01);
U.S. Cl.
CPC ...
H01M 14/005 (2013.01); H01M 8/18 (2013.01); H01M 8/188 (2013.01); H01M 2300/0014 (2013.01);
Abstract

Solar rechargeable battery combines the advantages of photoelectrochemical devices and batteries and has emerged as an attractive alternative to artificial photosynthesis for large-scale solar energy harvesting and storage. Due to the low photovoltages by the photoelectrodes, however, most previous demonstrations of unassisted photocharge have been realized on systems with low open circuit potentials (<0.8 V). In response to this critical challenge, here the present disclosure shows that the combined photovoltages exceeding 1.4 V can be obtained using a TaNnanotube photoanode and a GaN nanowire/Si photocathode with high photocurrents (>5 mA/cm). The photoelectrode system makes it possible to operate a 1.2 V alkaline anthraquinone/ferrocyanide redox battery with a high ideal solar-to-chemical conversion efficiency of 3.0% without externally applied potentials. Importantly, the photocharged battery was successfully discharged with a high voltage output.


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