The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.
The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.
Patent No.:
Date of Patent:
Nov. 24, 2020
Filed:
Jul. 24, 2019
Kamalesh Sirkar, Bridgewater, NJ (US);
Prithish Basak, Harrison, NJ (US);
John Chau, Belleville, NJ (US);
Kamalesh Sirkar, Bridgewater, NJ (US);
Prithish Basak, Harrison, NJ (US);
John Chau, Belleville, NJ (US);
Other;
Abstract
Reverse osmosis (RO) separation of organic solvent mixtures where solvent molecular weights <100 Da is challenging especially for powerful solvents that swell most uncrosslinked polymers. To avoid polymer swelling by solvents, a particular perfluoropolymer, perfluoro-2,2-dimethyl-1,3-dioxole copolymerized with tetrafluoroethylene, (PDD-TFE), designated CMS-7, was studied. This amorphous glassy extremely hydrophobic copolymer has a very high free volume (FV) fraction. The maximum radial dimension of FV regions is less than ˜0.65 nm allowing only single solvent molecule permeation. Further, interactions between polarity, dimensions and shapes of solvent molecules with those of polymer FV elements can lead to extraordinarily selective permeation. Permeation behaviors of other solvent mixtures, toluene-n-heptane, NMP-tetrahydrofuran, methanol-water, ethanol-water as well as individual phases of the immiscible mixture of NMP and the nonpolar solvent n-heptane were also studied.