The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 17, 2020

Filed:

Apr. 16, 2020
Applicant:

Shanghai Institute of Technology, Shanghai, CN;

Inventors:

Xiaoling Sun, Shanghai, CN;

Fei Li, Shanghai, CN;

Lingjun Ye, Shanghai, CN;

Zhilin Tang, Shanghai, CN;

Jinxin Zhao, Shanghai, CN;

Hehua Li, Shanghai, CN;

Assignee:
Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 51/255 (2006.01); C07C 51/235 (2006.01); C07C 45/29 (2006.01); B01J 31/02 (2006.01); B01J 31/18 (2006.01);
U.S. Cl.
CPC ...
C07C 51/255 (2013.01); B01J 31/0247 (2013.01); B01J 31/183 (2013.01); C07C 45/29 (2013.01); C07C 51/235 (2013.01); B01J 2231/70 (2013.01); B01J 2531/845 (2013.01);
Abstract

A process for preparing a ketone or carboxylic acid by catalytic oxidation of a secondary or primary alcohol comprises adding the secondary or primary alcohol as a raw material and N-hydroxyphthalimide (NHPI) combined with phthalocyanine, serving as a catalytic system, into an amount of an organic solvent into which oxygen gas is then introduced, to proceed with an oxidation reaction to give the ketone or carboxylic acid. The oxygen gas is employed as the source of an oxidant. The oxidation reaction may be carried out under normal pressure at 60 to 120° C. for 9 to 36 hours. The process can produce a high yield of ketone or carboxylic acid. Compared with conventional technology, the process has several advantages, such as the green oxidant, the cheap catalyst which can also be easily prepared and separated, and mild reaction conditions, and it is also an environmentally friendly process for alcohol oxidation.


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