The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 10, 2020

Filed:

Dec. 26, 2017
Applicant:

Kao Corporation, Tokyo, JP;

Inventor:

Takashi Aoki, Wakayama, JP;

Assignee:

KAO CORPORATION, Tokyo, JP;

Attorney:
Int. Cl.
CPC ...
C07D 319/06 (2006.01); C07D 317/32 (2006.01); C07C 215/10 (2006.01); C07C 45/65 (2006.01); C07C 49/17 (2006.01); C07D 407/12 (2006.01); C07B 61/00 (2006.01); C07C 213/00 (2006.01); C07B 41/12 (2006.01);
U.S. Cl.
CPC ...
C07D 407/12 (2013.01); C07B 61/00 (2013.01); C07C 45/65 (2013.01); C07C 213/00 (2013.01); C07D 317/32 (2013.01); C07D 319/06 (2013.01); C07B 41/12 (2013.01); C07C 49/17 (2013.01); C07C 215/10 (2013.01);
Abstract

The present invention is to provide a method of producing a glyceric acid ester which is easy for production and high in yield, and in which a pyridine to be used for the reaction is easily reused. Provided is a method of producing a compound represented by the following formula (II), including a step of oxidatively esterifying Compound A represented by the following formula (I) with Compound B selected from an organic nitroxyl radical, an N-hydroxy form thereof, and a salt containing an oxo ammonium cation of them, and an oxidizing agent in the presence of a pyridine having an alkyl substituent, wherein the use amount of Compound B is 0.0001 or more and 0.1 or less in terms of a molar ratio relative to Compound A: wherein, in the formulae (I) and (II), Rand Reach independently represent a hydrogen atom or a monovalent hydrocarbon group, or Rand Rare bonded to each other to form a divalent hydrocarbon group for constituting a ring structure.


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