The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 29, 2020

Filed:

Dec. 21, 2017
Applicant:

Dow Global Technologies Llc, Midland, MI (US);

Inventors:

Davy L. S. Nieskens, Terneuzen, NL;

Aysegul Ciftci Sandikci, Eindhoven, NL;

Peter E. Groenendijk, Ternezeun, NL;

Andrzej Malek, Midland, MI (US);

Assignee:

Dow Global Technologies LLC, Midland, MI (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C10G 2/00 (2006.01); C07C 1/04 (2006.01); B01J 23/06 (2006.01); B01J 23/26 (2006.01); B01J 29/85 (2006.01); B01J 37/18 (2006.01); C01B 39/54 (2006.01);
U.S. Cl.
CPC ...
C10G 2/33 (2013.01); B01J 23/06 (2013.01); B01J 23/26 (2013.01); B01J 29/85 (2013.01); B01J 37/18 (2013.01); C01B 39/54 (2013.01); C07C 1/043 (2013.01); C07C 1/0445 (2013.01); C10G 2/334 (2013.01); C07C 2523/06 (2013.01); C07C 2523/26 (2013.01); C07C 2529/85 (2013.01); C10G 2300/1022 (2013.01); C10G 2300/70 (2013.01); C10G 2400/20 (2013.01);
Abstract

A process for preparing Cto Colefins includes introducing a feed stream having a volumetric ratio of hydrogen to carbon monoxide from greater than 0.5:1 to less than 5:1 into a reactor, and contacting the feed stream with a bifunctional catalyst. The bifunctional catalyst includes a Cr/Zn oxide methanol synthesis component having a Cr to Zn molar ratio from greater than 1.0:1 to less than 2.15:1, and a SAPO-34 silicoaluminophosphate microporous crystalline material. The reactor operates at a temperature ranging from 350° C. to 450° C., and a pressure ranging from 10 bar (1.0 MPa) to 60 bar (6.0 MPa). The process has a cumulative productivity of Cto Colefins greater than 15 kg Cto Colefins/kg catalyst.


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