The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 15, 2020

Filed:

Jun. 26, 2019
Applicant:

Lyondell Chemical Technology, L.p., Houston, TX (US);

Inventors:

Sarthak Gaur, Houston, TX (US);

Robert John Rebman, Pearland, TX (US);

Daniel F. White, Houston, TX (US);

Joseph P. Longtin, Pasadena, TX (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 41/09 (2006.01); C07C 2/12 (2006.01); C10L 1/185 (2006.01); B01J 31/10 (2006.01);
U.S. Cl.
CPC ...
C07C 41/09 (2013.01); B01J 31/10 (2013.01); C07C 2/12 (2013.01); C10L 1/1852 (2013.01); C07C 2529/40 (2013.01); C10L 2270/023 (2013.01);
Abstract

A method of producing one or more glycerol ethers, the method comprising contacting glycerol and tertiary butanol (TBA) in the presence of an acidic catalyst to produce one or more glycerol ethers selected from mono-tert butyl glycerol ethers, di-tert butyl glycerol ethers, tri-tert butyl glycerol ethers, or a combination thereof; separating water and a stream comprising isobutylene, unreacted TBA, or a combination thereof from the one or more glycerol ethers; and recycling at least a portion of the stream comprising isobutylene, unreacted TBA, or a combination thereof to the contacting. Also disclosed is a process of co-producing isooctene, wherein the process involves contacting glycerol and tertiary butanol in the presence of a dehydrating catalyst and dimerizing/oligomerizing the dehydrated products in the presence of an oligomerizing catalyst to form isooctene, a precursor of isooctane and isomers thereof.


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