The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 08, 2020

Filed:

Dec. 16, 2016
Applicants:

Basf SE, Ludwigshafen am Rhein, DE;

Dow Global Technologies Llc, Midland, MI (US);

Inventors:

Edward O. Madenjian, Lake Jackson, TX (US);

Kenric A. Marshall, Lake Jackson, TX (US);

Assignees:

BASF SE, Ludwigshafen am Rhein, DE;

Dow Global Technologies LLC, Midland, MI (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07D 301/12 (2006.01); B01J 29/89 (2006.01); B01J 31/02 (2006.01); B01J 31/38 (2006.01);
U.S. Cl.
CPC ...
C07D 301/12 (2013.01); B01J 29/89 (2013.01); B01J 31/0259 (2013.01); B01J 31/38 (2013.01); B01J 2231/72 (2013.01); B01J 2531/002 (2013.01);
Abstract

A continuous process for the preparation of propylene oxide, comprising providing a liquid feed stream comprising propene, hydrogen peroxide, methanol, water, at least one dissolved potassium salt of hydroxyethylidenediphosphonic acid, and optionally propane; passing the liquid feed stream provided in (i) into an epoxidation reactor comprising a catalyst comprising a titanium zeolite of structure type MFI, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation reactor, obtaining a reaction mixture comprising propylene oxide, methanol, water, and the at least one dissolved potassium salt of hydroxyethylidenediphosphonic acid, and optionally propane; removing an effluent stream from the epoxidation reactor, the effluent stream comprising propylene oxide, methanol, water, at least a portion of the at least one potassium salt of hydroxyethylidenediphosphonic acid, and optionally propane.


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