The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 01, 2020

Filed:

Jul. 16, 2014
Applicant:

Invista North America S.a R.l., Wilmington, DE (US);

Inventors:

Sudhir N. V. K. Aki, Katy, TX (US);

James M. Garner, Wilmington, DE (US);

William J. Tenn, III, Beaumont, TX (US);

Thomas E. Vos, Beaumont, TX (US);

Assignee:

INVISTA North America S.a r.l., Wilmington, DE (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C07C 253/10 (2006.01); C07C 253/34 (2006.01); B01D 3/14 (2006.01); B01J 31/18 (2006.01);
U.S. Cl.
CPC ...
C07C 253/10 (2013.01); B01D 3/143 (2013.01); B01J 31/185 (2013.01); C07C 253/34 (2013.01);
Abstract

A solvent is at least partially separated from a catalyst. The catalyst comprises nickel and a bidentate phosphorus-containing ligand. The method for separation involves distilling a catalyst solution. The ratio of 2-pentenenitrile to 3-pentenenitrile in distillation column bottoms is controlled to reduce the amount of 3-pentenenitrile which is isomerized to form 2-methyl-3-butenenitrile. Isomerization of 3-pentenenitrile to 2-methyl-3-butenenitrile and subsequent isomerization of 2-methyl-3-butenenitrile to 2-methyl-2-butenenitrile, and/or hydrocyanation of 2-methyl-3-butenenitrile to methylglutaronitrile represents a loss in adiponitrile yield in a process for making adiponitrile.


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