The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 11, 2020

Filed:

Sep. 24, 2019
Applicant:

Css Nanotech, Inc., Houston, TX (US);

Inventors:

Daniel Hashim, Houston, TX (US);

Pulickel M. Ajayan, Houston, TX (US);

Mauricio Terrones, State College, PA (US);

Assignee:

CSS Nanotech, Inc., Houston, TX (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C02F 1/68 (2006.01); C01B 35/00 (2006.01); C02F 1/28 (2006.01); B82Y 30/00 (2011.01); B82Y 40/00 (2011.01); B01J 20/02 (2006.01); B01J 20/20 (2006.01); H01G 11/32 (2013.01); C01B 32/16 (2017.01); C02F 101/32 (2006.01); C02F 103/00 (2006.01); C02F 103/08 (2006.01);
U.S. Cl.
CPC ...
C02F 1/681 (2013.01); B01J 20/0248 (2013.01); B01J 20/0259 (2013.01); B01J 20/0266 (2013.01); B01J 20/205 (2013.01); B82Y 30/00 (2013.01); B82Y 40/00 (2013.01); C01B 32/16 (2017.08); C01B 35/00 (2013.01); C02F 1/288 (2013.01); H01G 11/32 (2013.01); B01J 2220/42 (2013.01); C01B 2202/30 (2013.01); C02F 1/281 (2013.01); C02F 1/283 (2013.01); C02F 2101/32 (2013.01); C02F 2103/007 (2013.01); C02F 2103/08 (2013.01); C02F 2305/08 (2013.01); Y02E 60/13 (2013.01); Y02W 10/37 (2015.05);
Abstract

Methods for synthesizing macroscale 3D heteroatom-doped carbon nanotube materials (such as boron doped carbon nanotube materials) and compositions thereof. Macroscopic quantities of three-dimensionally networked heteroatom-doped carbon nanotube materials are directly grown using an aerosol-assisted chemical vapor deposition method. The porous heteroatom-doped carbon nanotube material is created by doping of heteroatoms (such as boron) in the nanotube lattice during growth, which influences the creation of elbow joints and branching of nanotubes leading to the three dimensional super-structure. The super-hydrophobic heteroatom-doped carbon nanotube sponge is strongly oleophilic and can soak up large quantities of organic solvents and oil. The trapped oil can be burnt off and the heteroatom-doped carbon nanotube material can be used repeatedly as an oil removal scaffold. Optionally, the heteroatom-doped carbon nanotubes in the heteroatom-doped carbon nanotube materials can be welded to form one or more macroscale 3D carbon nanotubes.


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