The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 28, 2020

Filed:

Apr. 19, 2017
Applicant:

GM Global Technology Operations Llc, Detroit, MI (US);

Inventors:

Li Yang, Troy, MI (US);

Mei Cai, Bloomfield Hills, MI (US);

Peng Lu, Troy, MI (US);

Fang Dai, Troy, MI (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
H01M 10/0569 (2010.01); H01M 10/0525 (2010.01); H01M 10/0568 (2010.01); H01M 4/131 (2010.01); H01M 4/48 (2010.01); H01M 4/38 (2006.01);
U.S. Cl.
CPC ...
H01M 10/0569 (2013.01); H01M 4/386 (2013.01); H01M 4/483 (2013.01); H01M 10/0525 (2013.01); H01M 10/0568 (2013.01); H01M 2300/004 (2013.01); H01M 2300/0034 (2013.01); H01M 2300/0037 (2013.01);
Abstract

Electrochemical cells that cycle lithium ions are provided. The electrochemical cells have an electrode that includes a silicon-containing electroactive material that undergoes volumetric expansion and contraction during the cycling of the electrochemical cell; and an electrolyte system that promotes passive formation of a flexible protective layer comprising a lithium fluoride-polymer composite on one or more exposed surface regions of the silicon-containing electroactive material. The electrolyte system includes a lithium salt, at least one cyclic carbonate, and two or more linear carbonates. At least one of the two or more linear carbonate-containing co-solvents is a fluorinated carbonate-containing co-solvent. The electrolyte system accommodates the volumetric expansion and contraction of the silicon-containing electroactive material to promote long term cycling stability.


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