The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 14, 2020

Filed:

Jan. 14, 2016
Applicant:

Basf SE, Ludwigshafen, DE;

Inventors:

Diana Carolina Galeano Nunez, Mannheim, DE;

Christian Walsdorff, Ludwigshafen, DE;

Jürgen Zühlke, Speyer, DE;

Hans-Martin Allmann, Neunkirchen, DE;

Assignee:

BASF SE, , DE;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 23/22 (2006.01); B01J 35/00 (2006.01); B01J 37/02 (2006.01); B01J 23/00 (2006.01); B01J 27/198 (2006.01); B01J 35/10 (2006.01); B01J 23/18 (2006.01); B01J 21/06 (2006.01); C07C 51/265 (2006.01); C07C 51/31 (2006.01); B01J 37/08 (2006.01); C07D 307/89 (2006.01); B01J 35/02 (2006.01);
U.S. Cl.
CPC ...
B01J 23/22 (2013.01); B01J 21/063 (2013.01); B01J 23/002 (2013.01); B01J 23/18 (2013.01); B01J 27/198 (2013.01); B01J 35/0006 (2013.01); B01J 35/1004 (2013.01); B01J 37/0219 (2013.01); B01J 37/0221 (2013.01); B01J 37/0236 (2013.01); B01J 37/08 (2013.01); C07C 51/265 (2013.01); C07C 51/313 (2013.01); C07D 307/89 (2013.01); B01J 35/023 (2013.01); B01J 35/026 (2013.01); B01J 35/1014 (2013.01); B01J 37/0223 (2013.01); B01J 2523/00 (2013.01);
Abstract

The present invention relates to a catalyst system for oxidation of o-xylene and/or naphthalene to phthalic anhydride (PA) comprising at least four catalyst zones arranged in succession in the reaction tube and filled with catalysts of different chemical composition wherein the active material of the catalysts comprise vanadium and titanium dioxide and the active material of the catalyst in the last catalyst zone towards the reactor outlet has an antimony content (calculated as antimony trioxide) between 0.7 to 3.0 wt. %. The present invention further relates to a process for gas phase oxidation in which a gas stream comprising at least one hydrocarbon and molecular oxygen is passed through a catalyst system which comprises at least four catalyst zones arranged in succession in the reaction tube and filled with catalysts of different chemical composition wherein the active materials of the catalysts comprise vanadium and titanium dioxide and the active material of the catalyst in the last catalyst zone towards the reactor outlet has an antimony content (calculated as antimony trioxide) between 0.7 to 3.0 wt. %.


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