The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 07, 2020

Filed:

Jan. 16, 2017
Applicants:

Institute of Process Engineering, Chinese Academy of Sciences, Beijing, CN;

Beijing Zhongkaihongde Technology Co., Ltd, Beijing, CN;

Inventors:

Haitao Yang, Beijing, CN;

Qingshan Zhu, Beijing, CN;

Chuanlin Fan, Beijing, CN;

Qixun Ban, Beijing, CN;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
H01M 8/18 (2006.01); B01J 8/00 (2006.01); B01J 8/18 (2006.01); B01J 14/00 (2006.01); B01J 19/00 (2006.01); B01J 19/24 (2006.01); C01G 31/02 (2006.01);
U.S. Cl.
CPC ...
H01M 8/188 (2013.01); B01J 8/0055 (2013.01); B01J 8/1827 (2013.01); B01J 14/00 (2013.01); B01J 19/0013 (2013.01); B01J 19/245 (2013.01); C01G 31/02 (2013.01); H01M 8/18 (2013.01); B01J 2208/00752 (2013.01); B01J 2208/00761 (2013.01); B01J 2219/00074 (2013.01); H01M 2300/0011 (2013.01); Y02E 60/528 (2013.01);
Abstract

A system and method for producing a high-purity and high-activity vanadium electrolyte, comprising converting high-purity vanadium oxytrichloride into an ammonium salt in a fluidized bed by gas phase ammoniation, then in another fluidized bed, reducing the ammonium salt into a low-valence vanadium oxide having an average vanadium valence of 3.5, adding clean water and sulfuric acid for dissolution, and further performing activation by ultrasound to obtain a 3.5-valence vanadium electrolyte which can be directly used in a new all-vanadium redox flow battery stack. The method of producing an ammonium salt containing vanadium in the fluidized bed by gas phase ammoniation is of short process and high efficiency. Precise regulation of the valence state of the reduction product is implemented by arranging an internal member in the reduction fluidized bed, and ultrasonication is used to activate the vanadium ion, thereby greatly improving the activity of the electrolyte.


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