The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 07, 2020

Filed:

Oct. 02, 2015
Applicants:

Rohm and Haas Company, Philadelphia, PA (US);

Dow Global Technologies Llc, Midland, MI (US);

Inventors:

Zubin B. Kuvadia, Pearland, TX (US);

Kirk W. Limbach, Dresher, PA (US);

Dmitri A. Kraptchetov, Lansdale, PA (US);

Mark A. Silvano, Upper Black Eddy, PA (US);

Assignees:

Dow Global Technologies LLC, Midland, MI (US);

Rohm and Haas Company, Philadelphia, PA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 67/54 (2006.01); C07C 67/39 (2006.01); B01D 3/14 (2006.01); C07C 67/42 (2006.01);
U.S. Cl.
CPC ...
C07C 67/54 (2013.01); B01D 3/143 (2013.01); C07C 67/39 (2013.01); C07C 67/42 (2013.01);
Abstract

A process for continuously removing water in situ from an oxidative esterification reaction is provided. The process includes (a) conducting a first oxidative esterification reaction in a first reactor or reaction zone, wherein the total number of reactors or reaction zones is n and n is at least 2; (b) removing a crude product stream from the first reactor or reaction zone; (c) introducing the crude product stream to a distillation column to generate a column overheads stream and a column bottoms stream; (d) passing a portion of the columns bottoms stream to the product recovery zone; and (e) passing a portion of the column overheads stream to a subsequent reactor or reaction zone. Steps (a)-(e) can be repeated.


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