The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 30, 2020

Filed:

Mar. 17, 2016
Applicant:

Hrl Laboratories, Llc, Malibu, CA (US);

Inventors:

Andrew P. Nowak, Los Angeles, CA (US);

Adam F. Gross, Santa Monica, CA (US);

Elena Sherman, Culver City, CA (US);

Assignee:

HRL Laboratories, LLC, Malibu, CA (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C08G 18/50 (2006.01); C10M 169/04 (2006.01); C08G 18/66 (2006.01); C09D 175/08 (2006.01); C08G 65/34 (2006.01); C10M 107/44 (2006.01); C10M 147/04 (2006.01); C08G 81/00 (2006.01); C08G 81/02 (2006.01); C08G 18/75 (2006.01); C10M 107/38 (2006.01); C10M 149/20 (2006.01); C08G 18/65 (2006.01); C08G 18/48 (2006.01); C08G 18/38 (2006.01);
U.S. Cl.
CPC ...
C10M 169/041 (2013.01); C08G 18/3812 (2013.01); C08G 18/4804 (2013.01); C08G 18/5015 (2013.01); C08G 18/6505 (2013.01); C08G 18/6666 (2013.01); C08G 18/758 (2013.01); C08G 65/34 (2013.01); C08G 81/00 (2013.01); C08G 81/025 (2013.01); C09D 175/08 (2013.01); C10M 107/38 (2013.01); C10M 107/44 (2013.01); C10M 147/04 (2013.01); C10M 149/20 (2013.01); C10M 2201/062 (2013.01); C10M 2201/084 (2013.01); C10M 2201/103 (2013.01); C10M 2201/105 (2013.01); C10M 2213/0606 (2013.01); C10M 2217/0453 (2013.01); C10N 2220/021 (2013.01); C10N 2230/04 (2013.01); C10N 2230/06 (2013.01); C10N 2250/121 (2013.01);
Abstract

Low-friction fluorinated coatings are disclosed herein. A preferred low-friction material contains a low-surface-energy fluoropolymer having a surface energy between about 5 mJ/mto about 50 mJ/m, and a hygroscopic material that is covalently connected to the fluoropolymer in a triblock copolymer, such as PEG-PFPE-PEG. The material forms a lubricating surface layer in the presence of humidity. An exemplary copolymer comprises fluoropolymers with average molecular weight from 500 g/mol to 20,000 g/mol, wherein the fluoropolymers are (α,ω)-hydroxyl-terminated and/or (α,ω)-amine-terminated, and wherein the fluoropolymers are present in the triblock structure T-(CH—CH—O)—CH—CF—O—(CF—CF—O)(CF—O)—CF—CH—(O—CH—CH)-T where T is a hydroxyl or amine terminal group, p=1 to 50, m=1 to 100, and n=1 to 100. The copolymer also contains isocyanate species and polyol or polyamine chain extenders or crosslinkers possessing a functionality of preferably 3 or greater. These durable, solvent-resistant, and transparent coatings reduce insect debris following impact.


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