The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 23, 2020

Filed:

Oct. 11, 2018
Applicants:

East China University of Science and Technology, Shanghai, CN;

Shanghai Fuyuan Rubber and Plastic Technology Ltd., Shanghai, CN;

Inventors:

Anna Zheng, Shanghai, CN;

Yong Guan, Shanghai, CN;

Dafu Wei, Shanghai, CN;

Xiang Xu, Shanghai, CN;

Pengfei Zhan, Shanghai, CN;

Weixing Liu, Shanghai, CN;

Han Shi, Shanghai, CN;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F 220/14 (2006.01); C08F 2/10 (2006.01); C08F 212/08 (2006.01); C08F 265/06 (2006.01); C08F 287/00 (2006.01); C08L 25/14 (2006.01); C08L 35/06 (2006.01); C08L 77/06 (2006.01); C08F 2/01 (2006.01); C08F 2/44 (2006.01); C08F 212/10 (2006.01); C08K 5/00 (2006.01);
U.S. Cl.
CPC ...
C08F 220/14 (2013.01); C08F 2/01 (2013.01); C08F 2/44 (2013.01); C08F 212/08 (2013.01); C08F 212/10 (2013.01); C08F 265/06 (2013.01); C08F 287/00 (2013.01); C08K 5/005 (2013.01); C08L 25/14 (2013.01); C08L 35/06 (2013.01); C08L 77/06 (2013.01); C08F 2800/20 (2013.01); C08K 2201/011 (2013.01); C08L 2201/08 (2013.01); C08L 2205/03 (2013.01);
Abstract

A method of reactive extrusion copolymerization of vinyl monomer consisting of (1) feeding vinyl monomer or at least one vinyl monomer together with an initiator into the first screw of twin-screw extruder, and modified resin into the subsequent screw section; (2) feeding the above monomer into the screw segment after auto-acceleration zone and feeding the initiator corresponding to the temperature of barrel and micro/nano inorganic modified fillers after the half-life period of the initiator; (3) feeding the antioxidant and anti-UV agent at the end of the polymerization, and then removing unpolymerized monomer and by-products by devolatilization of screw segment; (4) obtaining vinyl copolymer resin with a anticipated molecular weight of 5×102 to 6×105 from the reactive extrusion polymerization by controlling the temperature of different screw segments. The invention which overcomes the existing defects of the free radical polymerization by reactive extrusion technology, can not only meet the requirement of short stay time of reactive extrusion polymerization, combine the functionalization and high performance, but also make it possible to obtain high molecular weight polymers.


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