The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 09, 2020

Filed:

Dec. 20, 2016
Applicants:

Total Raffinage Chimie, La Défense, FR;

Eth Zurich, Zurich, CH;

Inventors:

Daniel Curulla-Ferre, Uccle, BE;

Charlotte Drouilly, Uccle, BE;

Oliver Martin, Zürich, CH;

Cecilia Mondelli, Zürich, CH;

Javier Perez-Ramirez, Zürich, CH;

Antonio J. Martin-Fernandez, Dietikon, CH;

Assignees:

TOTAL RAFFINAGE CHIMIE, Courbevoie, FR;

ETH ZURICH, Zurich, CH;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 29/151 (2006.01); C07C 29/153 (2006.01); B01J 21/06 (2006.01); B01J 23/08 (2006.01); B01J 23/22 (2006.01); B01J 21/10 (2006.01); B01J 21/08 (2006.01); B01J 23/26 (2006.01); B01J 21/04 (2006.01); B01J 23/10 (2006.01); B01J 23/06 (2006.01); B01J 23/14 (2006.01); B01J 21/00 (2006.01); C07C 31/04 (2006.01); B01J 35/02 (2006.01); B01J 35/10 (2006.01);
U.S. Cl.
CPC ...
C07C 29/153 (2013.01); B01J 21/00 (2013.01); B01J 21/04 (2013.01); B01J 21/063 (2013.01); B01J 21/066 (2013.01); B01J 21/08 (2013.01); B01J 21/10 (2013.01); B01J 23/06 (2013.01); B01J 23/08 (2013.01); B01J 23/10 (2013.01); B01J 23/14 (2013.01); B01J 23/22 (2013.01); B01J 23/26 (2013.01); C07C 29/151 (2013.01); B01J 35/023 (2013.01); B01J 35/1014 (2013.01); B01J 35/1019 (2013.01); B01J 35/1038 (2013.01); B01J 35/1042 (2013.01); B01J 35/1047 (2013.01); B01J 2523/3712 (2013.01); B01J 2531/33 (2013.01); C07C 31/04 (2013.01);
Abstract

The invention relates to a process for methanol synthesis comprising the steps of providing a syngas feed stream comprising hydrogen and a mixture of carbon dioxide and carbon monoxide, wherein carbon dioxide represents from 1 to 50 mol % of the total molar content of the feed stream, carbon monoxide is contained from 0.1 to 85 mol % of the total molar content, and His comprised from 5 to 95 mol % of the total molar content of the feed stream; providing an indium oxide catalyst selected from a bulk catalyst and a supported catalyst comprising indium oxide (InO) as the main active phase; putting in contact said stream with said catalyst at a reaction temperature of at least 373 K (99.85° C.) and under a pressure ranging of at least 1 MPa; and recovering the methanol effluents. The invention also relates to an indium oxide based catalyst.


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