The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 26, 2020

Filed:

Nov. 06, 2017
Applicant:

Exxonmobil Chemical Patents Inc., Baytown, TX (US);

Inventors:

Dongming Li, Houston, TX (US);

Ching-Tai Lue, Sugarland, TX (US);

Phillip T. Matsunaga, Houston, TX (US);

Mark B. Davis, Lake Jackson, TX (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F 2/04 (2006.01); C08F 4/14 (2006.01); C08F 210/16 (2006.01); C08F 4/659 (2006.01); C08F 4/6592 (2006.01);
U.S. Cl.
CPC ...
C08F 4/14 (2013.01); C08F 4/65904 (2013.01); C08F 4/65912 (2013.01); C08F 210/16 (2013.01); C08F 4/6592 (2013.01); C08F 4/65908 (2013.01); C08F 4/65916 (2013.01); C08F 4/65925 (2013.01); C08F 2410/01 (2013.01); C08F 2420/02 (2013.01);
Abstract

Borate activated catalyst systems and methods for making the same for gas phase or slurry phase olefin polymerization are provided. The catalyst system can include a first catalyst comprising a borate activated mono cyclopentadienyl metallocene compound and a second catalyst comprising a supported bis cyclopentadienyl metallocene complex. A supported bis cyclopentadienyl metallocene complex can be prepared to provide a preformed, supported catalyst, wherein the supported bis cyclopentadienyl metallocene complex comprises bis(1,3-methylbutyl cyclopentadienyl) zirconium dichloride. The preformed, supported catalyst can be mixed with mineral oil or hydrocarbon solvent to form a slurry. The slurry can be mixed with a borate activated mono cyclopentadienyl metallocene compound to form the borate activated catalyst system.


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