The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 19, 2020

Filed:

Feb. 22, 2017
Applicant:

Dow Global Technologies Llc, Midland, MI (US);

Inventors:

Andrzej Malek, Midland, MI (US);

David Gordon Barton, Midland, MI (US);

Lin Luo, Freeport, TX (US);

Assignee:

Dow Global Technologies LLC, Midland, MI (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 38/44 (2006.01); B01J 38/18 (2006.01); B01J 23/62 (2006.01); B01J 23/96 (2006.01); B01J 38/30 (2006.01); B01J 38/34 (2006.01); B01J 23/08 (2006.01); B01J 23/92 (2006.01); C07C 5/32 (2006.01); B01J 38/14 (2006.01); B01J 35/10 (2006.01); B01J 38/02 (2006.01); B01J 35/02 (2006.01); B01J 21/12 (2006.01);
U.S. Cl.
CPC ...
B01J 38/44 (2013.01); B01J 21/12 (2013.01); B01J 23/08 (2013.01); B01J 23/62 (2013.01); B01J 23/92 (2013.01); B01J 23/96 (2013.01); B01J 35/023 (2013.01); B01J 35/1014 (2013.01); B01J 38/02 (2013.01); B01J 38/14 (2013.01); B01J 38/18 (2013.01); B01J 38/30 (2013.01); B01J 38/34 (2013.01); C07C 5/321 (2013.01); C07C 5/325 (2013.01); C07C 2523/58 (2013.01); C07C 2523/62 (2013.01); Y02P 20/52 (2015.11); Y02P 20/584 (2015.11);
Abstract

The present disclosure provides an air-soak containing regeneration process reducing its time. The process includes (i) removing surface carbon species from a gallium-based alkane dehydrogenation catalyst in a combustion process in the presence of a fuel gas; (ii) conditioning the gallium-based alkane dehydrogenation catalyst after (i) in air-soak treatment at a temperature of 660° C. to 850° C. with (iii) a flow of oxygen-containing gas having (iv) 0.1 to 100 parts per million by volume (ppmv) of a chlorine source selected from chlorine, a chlorine compound or a combination thereof; and achieving a predetermined alkane conversion percentage for the gallium-based alkane dehydrogenation catalyst undergoing the air-soak containing regeneration process using (i) through (iv) 10% to 50% sooner in air-soak treatment than that required to achieve the same predetermined alkane conversion percentage for the gallium-based alkane dehydrogenation catalyst undergoing the air-soak containing regeneration process using (i) through (iii), but without (iv).


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