The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 12, 2020

Filed:

Oct. 16, 2015
Applicant:

Albemarle Corporation, Baton Rouge, LA (US);

Inventors:

Chi Hung Cheng, Baton Rouge, LA (US);

Jackson R. Switzer, Kings Mountain, NC (US);

Jan Nieman, Maarssen, NL;

Assignee:

ALBEMARLE CORPORATION, Charlotte, NC (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C22B 26/12 (2006.01); C01D 15/04 (2006.01); B01J 20/04 (2006.01); B01J 20/28 (2006.01); B01J 20/30 (2006.01); B01J 20/08 (2006.01);
U.S. Cl.
CPC ...
C22B 26/12 (2013.01); B01J 20/041 (2013.01); B01J 20/046 (2013.01); B01J 20/08 (2013.01); B01J 20/28004 (2013.01); B01J 20/28057 (2013.01); B01J 20/3085 (2013.01); C01D 15/04 (2013.01); B01J 2220/56 (2013.01);
Abstract

Producing high purity lithium solution from a lithium source containing dissolved Na, Ca, and Mg, by: passing the source into and out of a bed of sorbent composed of hydrated alumina intercalated with LiX, preferably LiCl, to extract lithium from the lithium source into the sorbent; washing the bed of sorbent with dilute aqueous LiCl to remove lithium from the sorbent to obtain a lithium eluent of increased Liconcentration; subjecting this eluent to nanofiltration to produce a lithium permeate from which Ca2+, Mg2+, and other nanofilterable components are concurrently removed, yielding a permeate solution with 25% or less, and a retentate solution with 75% or more Caand Mg, as compared to the eluent from washing; and subjecting the permeate solution to a particular forward osmosis yielding a solution having 13,000-25,000 ppm dissolved lithium. Specified optional steps and new features can be used to increase lithium concentrations and purity.


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