The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 12, 2020

Filed:

Oct. 11, 2016
Applicant:

Basf SE, Ludwigshafen am Rhein, DE;

Inventors:

Thomas Schaub, Ludwigshafen am Main, DE;

Rocco Paciello, Ludwigshafen am Main, DE;

Martin Ernst, Ludwigshafen am Main, DE;

Jaroslaw Mormul, Mannheim, DE;

Peter Hofmann, Heidelberg, DE;

Jan Breitenfeld, Niederbipp, CH;

Oliver Trapp, Munich, DE;

Assignee:

BASF SE, , DE;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 51/14 (2006.01); C07C 51/305 (2006.01); C07C 67/42 (2006.01); C07C 29/132 (2006.01); C07C 209/26 (2006.01); C07D 317/12 (2006.01); C07D 319/06 (2006.01); B01J 31/18 (2006.01); C08G 69/28 (2006.01);
U.S. Cl.
CPC ...
C07C 51/14 (2013.01); B01J 31/185 (2013.01); B01J 31/186 (2013.01); C07C 29/132 (2013.01); C07C 51/305 (2013.01); C07C 67/42 (2013.01); C07C 209/26 (2013.01); C07D 317/12 (2013.01); C07D 319/06 (2013.01); C08G 69/28 (2013.01); B01J 2231/321 (2013.01); B01J 2231/349 (2013.01); B01J 2531/822 (2013.01); B01J 2540/10 (2013.01);
Abstract

The invention relates to a process for the production of 1,6-difunctionalized hexane derivatives from 1,3-diunsaturated hydrocarbons, preferably butadiene, wherein a hydroformylation with carbon monoxide and hydrogen is performed in the presence of an at least dihydric alkanol and during the hydroformylation the temperature is increased. The reaction yields the acetals of the 1,6-hexanedial derivatives which are isolated and further reacted to obtain the desired 1,6-difunctionalized hexane derivatives, in particular 1,6-hexanediamine, 1,6-hexanediol and adipic acid.


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