The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 05, 2020

Filed:

Jun. 26, 2018
Applicant:

Exxonmobil Research and Engineering Company, Annandale, NJ (US);

Inventors:

Partha Nandi, Annandale, NJ (US);

Matthew S. Ide, Doylestown, PA (US);

Jihad M. Dakka, Whitehouse Station, NJ (US);

Quddus A. Nizami, Spring, TX (US);

Mobae Afeworki, Phillipsburg, NJ (US);

Assignee:
Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
B01J 29/06 (2006.01); B01J 29/70 (2006.01); C10G 29/20 (2006.01); C07C 2/66 (2006.01); C10G 29/12 (2006.01); B01J 37/02 (2006.01); B01J 37/00 (2006.01); B01J 37/08 (2006.01); B01J 37/26 (2006.01); C07C 2/12 (2006.01); C07C 2/68 (2006.01);
U.S. Cl.
CPC ...
B01J 29/7088 (2013.01); B01J 29/7038 (2013.01); B01J 37/0009 (2013.01); B01J 37/0201 (2013.01); B01J 37/023 (2013.01); B01J 37/08 (2013.01); B01J 37/26 (2013.01); C07C 2/12 (2013.01); C07C 2/66 (2013.01); C07C 2/68 (2013.01); C10G 29/12 (2013.01); C10G 29/205 (2013.01); B01J 2229/18 (2013.01); B01J 2229/183 (2013.01); B01J 2229/186 (2013.01); B01J 2229/20 (2013.01); B01J 2229/42 (2013.01); C07C 2529/70 (2013.01);
Abstract

Catalyst compositions with improved alkylation activity and corresponding methods for making such catalyst compositions are provided. The catalyst(s) correspond to solid acid catalysts formed by exposing a catalyst precursor with a zeolitic framework structure to a molten metal salt that includes fluorine, such as a molten metal fluoride. The resulting fluorinated solid acid catalysts can have improved alkylation activity while having a reduced or minimized amount of structural change due to the exposure to the molten metal fluoride. This is in contrast to fluorinated solid acid catalysts that are exposed to higher severity forms of fluorination, such as exposure to ammonium fluoride or HF. SnFis an example of a suitable molten metal fluoride.


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