The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 24, 2020

Filed:

Jun. 10, 2016
Applicant:

Compact Membrane Systems, Inc., Newport, DE (US);

Inventors:

Ning Shangguan, Cherry Hill, NJ (US);

Andrew Edward Feiring, Wilmington, DE (US);

Sudipto Majumdar, Newark, DE (US);

Assignee:

COMPACT MEMBRANE SYSTEMS, INC., Newport, DE (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
B01D 71/32 (2006.01); B01D 53/22 (2006.01); C08F 214/18 (2006.01); C07C 17/38 (2006.01); B01D 71/76 (2006.01); B01D 67/00 (2006.01); B01D 71/52 (2006.01);
U.S. Cl.
CPC ...
B01D 71/32 (2013.01); B01D 53/228 (2013.01); B01D 67/0006 (2013.01); B01D 71/76 (2013.01); C07C 17/38 (2013.01); C08F 214/186 (2013.01); B01D 71/52 (2013.01); B01D 2323/06 (2013.01); B01D 2323/08 (2013.01); B01D 2325/20 (2013.01);
Abstract

Membranes having a permselective active layer of a copolymerized perfluorinated monomer and an non-fluorinated alkylvinylester monomer demonstrate superior selective permeability performance for separating gas mixtures compared to membranes of exclusively perfluorinated polymers. Preferred active layer compositions are copolymers of perfluoro-2,2-dimethyl-1,3 dioxole (PDD) copolymerized with an alkylvinyl ester such as vinyl acetate, and vinyl pivalate, and with alkylvinyl esters that are substantially hydrolyzed to provide copolymerized vinyl alcohol functionality. The membranes can have a thin, high diffusion rate, 'gutter layer' of a fluorinated polymer highly permeable to nitrogen positioned between the active layer and a porous support layer. A novel copolymer effective in selectively permeable membranes is a copolymer of PDD and an alkylvinyl ester compound having the formula HC═CHOC(O)Rin which Ris a linear or branched alkyl group of from 2 to 5 carbon atoms.


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