The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 17, 2020

Filed:

Jun. 25, 2018
Applicant:

Zhejiang Quhua Fluor-chemistry CO Ltd, Zhejiang, CN;

Inventors:

Jiangyong Hong, Zhejiang, CN;

Bo Yang, Zhejiang, CN;

Yan Zhang, Zhejiang, CN;

Guojun Yu, Zhejiang, CN;

Yang Zhao, Zhejiang, CN;

Hao Ouyang, Zhejiang, CN;

Haitao Gong, Zhejiang, CN;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 17/20 (2006.01); B01J 21/04 (2006.01); B01J 23/26 (2006.01); C07C 17/21 (2006.01); C07C 17/358 (2006.01); B01J 23/60 (2006.01); B01J 23/62 (2006.01); C07C 17/383 (2006.01); C07C 21/18 (2006.01); B01J 23/58 (2006.01);
U.S. Cl.
CPC ...
C07C 17/206 (2013.01); B01J 21/04 (2013.01); B01J 23/26 (2013.01); B01J 23/58 (2013.01); B01J 23/60 (2013.01); B01J 23/62 (2013.01); C07C 17/21 (2013.01); C07C 17/358 (2013.01); C07C 17/383 (2013.01); C07C 21/18 (2013.01);
Abstract

Disclosed is a method for co-producing various alkenyl halides and hydrofluoroalkanes: cis-1-chloro-3,3,3-trifluoropropene is introduced into a first reactor to carry out an isomerization reaction in the presence of a first catalyst, and the reaction product is rectified to obtain a product trans-1-chloro-3,3,3-trifluoropropene; and 30-70 wt % of trans-1-chloro-3,3,3-trifluoropropene and hydrogen fluoride are mixed and then introduced into a second reactor to carry out a reaction in the presence of a second catalyst to obtain a second reactor reaction product; the second reactor reaction product is introduced into a phase separator for separation, and the obtained organic phase is rectified to obtain the products trans-1,3,3,3-tetrafluoropropene, cis-1,3,3,3-tetrafluoropropene and 1,1,1,3,3-pentafluoropropane. The invention has the advantages of simple process, high efficiency, high operation flexibility, less investment and low energy consumption.


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