The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 03, 2020

Filed:

Nov. 13, 2018
Applicant:

Eastman Chemical Company, Kingsport, TN (US);

Inventors:

Sumit Chakraborty, Johnson City, TN (US);

Steven J. Adams, Gray, TN (US);

Robert Thomas Hembre, Johnson City, TN (US);

Scott Donald Barnicki, Kingsport, TN (US);

David Alan Jenkins, Jonesborough, TN (US);

Assignee:

Eastman Chemical Company, Kingsport, TN (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 67/44 (2006.01); C07C 67/39 (2006.01); B01J 31/18 (2006.01); B01J 31/24 (2006.01); B01J 31/22 (2006.01); C07C 69/003 (2006.01);
U.S. Cl.
CPC ...
C07C 67/44 (2013.01); B01J 31/1815 (2013.01); B01J 31/2295 (2013.01); B01J 31/2404 (2013.01); C07C 67/39 (2013.01); B01J 2231/46 (2013.01); B01J 2531/821 (2013.01); C07C 69/003 (2013.01);
Abstract

A process for making methyl esters in high yields. The process comprises contacting aliphatic or aromatic aldehydes and methanol with a homogeneous dimeric ruthenium catalyst, to catalyze the dehydrogenative coupling between aliphatic or aromatic aldehydes and methanol. The reaction is highly selective (<99.9%) toward the formation of methyl esters over homoesters and alcohols and operates at temperatures of less than 100° C. for 2-8 hours.


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