The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 21, 2020

Filed:

Feb. 04, 2019
Applicant:

Exxonmobil Chemical Patents Inc., Baytown, TX (US);

Inventors:

Jo Ann M. Canich, Houston, TX (US);

Rainer Kolb, Kingwood, TX (US);

Periagaram S. Ravishankar, Kingwood, TX (US);

Phillip T. Matsunaga, Houston, TX (US);

Peijun Jiang, Katy, TX (US);

Rhutesh K. Shah, Katy, TX (US);

Narayanaswami Dharmarajan, Houston, TX (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08L 23/16 (2006.01); C08L 23/08 (2006.01); C08F 2/00 (2006.01); C08F 4/76 (2006.01); C08F 210/06 (2006.01); C08F 210/18 (2006.01); C08F 210/16 (2006.01); C08F 4/659 (2006.01);
U.S. Cl.
CPC ...
C08L 23/16 (2013.01); C08F 2/001 (2013.01); C08F 4/76 (2013.01); C08F 210/06 (2013.01); C08F 210/16 (2013.01); C08F 210/18 (2013.01); C08F 4/65908 (2013.01); C08F 2500/09 (2013.01); C08F 2500/17 (2013.01); C08L 2205/02 (2013.01); C08L 2205/025 (2013.01); C08L 2205/06 (2013.01); C08L 2207/07 (2013.01); C08L 2312/04 (2013.01); C08L 2314/06 (2013.01);
Abstract

Provided herein are polymerization processes and polymer compositions including reactor blends formed by such polymerization processes. The polymerization processes include copolymerization using two metallocene catalyst systems: the first catalyst system capable of producing polymers having 60% or more vinyl terminations, the second catalyst system capable of producing high molecular weight polymers, preferably incorporating at least some of the polymers produced by the first catalyst system into the high molecular weight polymers. The reactor blends formed thereby therefore include first and second copolymer components, which may differ in monomer content and weight-average molecular weight (Mw). Furthermore, the reactor blends may exhibit advantageous rheological properties, at least some of which are consistent with long-chain branching. Preferred reactor blends comprise ethylene-propylene-diene (EPDM) terpolymers.


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