The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 31, 2019

Filed:

Nov. 28, 2013
Applicant:

Phosphonics Ltd, Oxford, GB;

Inventors:

Paul Murray, Yate, GB;

Robin Wilkes, Oxford, GB;

Christopher North, Oxford, GB;

Assignees:

PHOSPHONICS LTD, Oxford, Oxfordshire, GB;

Other;

Attorneys:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07F 7/10 (2006.01); C08G 77/385 (2006.01); C08G 77/388 (2006.01); C08G 77/392 (2006.01); C08G 77/395 (2006.01); B01J 31/06 (2006.01); B01J 31/16 (2006.01); B01J 31/24 (2006.01); C07F 7/08 (2006.01); C07F 17/02 (2006.01);
U.S. Cl.
CPC ...
C07F 7/10 (2013.01); B01J 31/069 (2013.01); B01J 31/1633 (2013.01); B01J 31/1658 (2013.01); B01J 31/2409 (2013.01); C07F 7/0834 (2013.01); C07F 17/02 (2013.01); C08G 77/385 (2013.01); C08G 77/388 (2013.01); C08G 77/392 (2013.01); C08G 77/395 (2013.01); B01J 2231/321 (2013.01); B01J 2231/42 (2013.01); B01J 2231/4211 (2013.01); B01J 2531/0205 (2013.01); B01J 2531/16 (2013.01); B01J 2531/80 (2013.01); B01J 2531/824 (2013.01); B01J 2531/842 (2013.01); B01J 2531/847 (2013.01); Y02P 20/588 (2015.11);
Abstract

A process for the selective removal of a component from a liquid phase and subsequently returning the component to a liquid phase is disclosed. A novel compound of formula (I) [SUP]-[[L]-[G]]a (I) in which L is a linking group, G is an aryl group having a leaving group LG selected from Cl, Br, I, sulfonate such as triflate, a diazo group, a nitrile, an ester and an alkoxy group and substituent Q is selected from H, NR2, OR, CO2R, F, Cl, NO2 CN and SUP is a support having a plurality of groups -[L]-[G] bound to the support is contacted with the liquid phase to bind the component to the compound I thereby forming a captured component which is separated from and may be returned to the liquid phase. The compound I is especially useful in binding homogeneous catalysts to remove it from a reaction medium and selectively returning the catalyst to the reaction medium at a later stage. The compound is particularly useful for cross-coupling reactions, for example in Suzuki reactions.


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