The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 24, 2019

Filed:

Jun. 26, 2014
Applicant:

3m Innovative Properties Company, St. Paul, MN (US);

Inventors:

Christopher B. Walker, Jr., St. Paul, MN (US);

John C. Clark, Maplewood, MN (US);

Tatsuo Fukushi, Woodbury, MN (US);

Thomas P. Klun, Lakeland, MN (US);

Vivek Krishnan, St. Paul, MN (US);

Alexander J. Kugel, Woodbury, MN (US);

Lan H. Liu, Rosemount, MN (US);

Jingjing Ma, Cottage Grove, MN (US);

Steven J. McMan, Stillwater, MN (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C09D 127/18 (2006.01); C09D 127/12 (2006.01); C09D 5/00 (2006.01); C09D 127/16 (2006.01); C09D 127/20 (2006.01); C08K 7/18 (2006.01); C08K 7/20 (2006.01);
U.S. Cl.
CPC ...
C09D 127/18 (2013.01); C09D 5/00 (2013.01); C09D 127/12 (2013.01); C09D 127/16 (2013.01); C09D 127/20 (2013.01); C08K 7/18 (2013.01); C08K 7/20 (2013.01);
Abstract

There is provided an article comprising at least a first surface having a fluorine-containing polymeric binder resin layer and a plurality of microspheres partially embedded in a first major surface of the binder resin layer and adhered thereto; wherein the fluorine-containing polymer is derived in part from at least one partially fluorinated, or non-fluorinated, monomer; and wherein the article exhibits a stain resistance to yellow mustard at elevated temperature and humidity as measured by the change in b* of less than 50. There are also provided such articles wherein the fluorine-containing polymer is derived in part from at least one partially fluorinated, or non-fluorinated, monomer; and wherein the fluorine content along the polymeric backbone of the fluorine-containing polymer is from about 27% to 72% by weight. There are also provided such articles wherein the article is a thermoformable article exhibiting chemical resistance according to ASTM D5402-06.


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