The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 24, 2019

Filed:

May. 23, 2017
Applicants:

The Regents of the University of California, Oakland, CA (US);

Chevron U.s.a. Inc., San Ramon, CA (US);

Inventors:

Trenton Otto, Berkeley, CA (US);

Enrique Iglesia, Berkeley, CA (US);

Stacey Ian Zones, San Francisco, CA (US);

Assignees:

The Regents of the University of California, Oakland, CA (US);

Chevron U.S.A. Inc., San Ramon, CA (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
B01D 53/86 (2006.01); B01J 23/42 (2006.01); B01J 23/44 (2006.01); B01J 23/52 (2006.01); B01J 29/74 (2006.01); B01J 35/00 (2006.01); B01J 37/00 (2006.01); B01J 37/04 (2006.01); B01J 37/10 (2006.01); B01J 37/14 (2006.01); B01J 37/18 (2006.01); C07C 1/20 (2006.01);
U.S. Cl.
CPC ...
B01J 29/74 (2013.01); B01D 53/8628 (2013.01); B01J 23/42 (2013.01); B01J 23/44 (2013.01); B01J 23/52 (2013.01); B01J 35/0006 (2013.01); B01J 35/0013 (2013.01); B01J 37/009 (2013.01); B01J 37/04 (2013.01); B01J 37/10 (2013.01); B01J 37/14 (2013.01); B01J 37/18 (2013.01); C07C 1/20 (2013.01); B01D 2255/50 (2013.01); C07C 2523/42 (2013.01); C07C 2523/44 (2013.01); C07C 2523/52 (2013.01); C07C 2529/74 (2013.01);
Abstract

Zeolites having highly dispersed bimetallic clusters, uniformly distributed in size and composition, encapsulated therein are disclosed. Metal encapsulation and alloying is conferred by introducing ligated metal cation precursors into zeolite synthesis gels, which are subsequently crystallized hydrothermally to form zeolites with metal cations occluded in the pores. The ligated cations are anchored to the zeolite framework via siloxane bridges which enforces their uniform dispersion throughout the zeolite crystals. Treatment of the crystallized zeolites in Oand then Hforms bimetallic clusters, which remain narrowly distributed in size and composition.


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