The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 26, 2019

Filed:

Mar. 11, 2016
Applicant:

Council of Scientific & Industrial Research, New Delhi, IN;

Inventors:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 269/00 (2006.01); C07C 68/00 (2006.01); B01J 19/24 (2006.01);
U.S. Cl.
CPC ...
C07C 269/00 (2013.01); B01J 19/2415 (2013.01); C07C 68/00 (2013.01); B01J 2219/00051 (2013.01); B01J 2219/24 (2013.01);
Abstract

The present invention discloses an improved catalyst free process for synthesis of alkyl carbamates in an integrated system comprising a tubular reactor and a striper. The process comprises reacting urea and an alcohol in said tubular reactor under autogeneous pressure; wherein said process provides >90% selectivity towards alkyl carbamate. The mixture of urea and alcohol is N fed to the tubular reactor at a particular feed rate. The tubular reactor is heated externally under autogeneous pressure to carry out a synthesis reaction producing alkyl carbamate and ammonia. The ammonia is removed from the tubular reactor by the striper. The tubular reactor and the stripper are arranged in series to reduce the equilibrium limitations of the reaction and drive the reaction in forward direction.


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