The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 05, 2019

Filed:

May. 20, 2015
Applicants:

Compagnie Generale Des Etablissements Michelin, Clermont-Ferrand, FR;

Michelin Recherche ET Technique S.a., Granges-Paccot, CH;

Inventors:

Wendelin Jan Stark, Langenthal, CH;

Robert Nikolaus Grass, Zurich, CH;

Milan Fedurco, Clermont-Ferrand, FR;

Antonio Delfino, Clermont-Ferrand, FR;

Jean-Paul Meraldi, Zurich, CH;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C23C 16/00 (2006.01); C23C 4/129 (2016.01); D07B 1/06 (2006.01); C23C 4/04 (2006.01); C01B 32/184 (2017.01); C01B 32/194 (2017.01); B60C 9/00 (2006.01);
U.S. Cl.
CPC ...
C23C 4/129 (2016.01); B60C 9/00 (2013.01); C01B 32/184 (2017.08); C01B 32/194 (2017.08); C23C 4/04 (2013.01); D07B 1/0666 (2013.01); B60C 2009/0014 (2013.01); D07B 2201/2011 (2013.01); D07B 2201/2013 (2013.01); D07B 2205/3007 (2013.01); D07B 2205/3021 (2013.01); D07B 2205/3067 (2013.01); D07B 2205/3071 (2013.01); D07B 2205/3085 (2013.01); D07B 2205/3089 (2013.01); D07B 2205/3092 (2013.01);
Abstract

A process for depositing, with forward progression, graphene on the surface of a metallic or metallized continuous reinforcer, at the periphery of which is positioned a layer of surface metal chosen from copper, nickel and copper/nickel alloys, comprises at least one stage of flame spray pyrolysis ('FSP'), under a reducing atmosphere, of a carbon precursor which generates, in the flame, at least one carbon-based gas such as carbon monoxide which is sprayed onto the surface of the reinforcer in forward progression, and is decomposed thereon to form one or more graphene layers at the surface of the surface metal; an additional stage of graphene functionalization makes it possible to adhere the reinforcer to a polymer matrix such as rubber.


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