The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 05, 2019

Filed:

Jun. 06, 2016
Applicant:

Synvina C.v., Amsterdam, NL;

Assignee:

Synvina C.V., Amsterdam, NL;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07D 307/68 (2006.01); B01J 23/34 (2006.01); B01J 23/75 (2006.01); B01J 27/08 (2006.01); C07B 31/00 (2006.01); C07B 33/00 (2006.01); C07B 41/02 (2006.01); C07B 63/02 (2006.01);
U.S. Cl.
CPC ...
C07D 307/68 (2013.01); B01J 23/34 (2013.01); B01J 23/75 (2013.01); B01J 27/08 (2013.01); C07B 31/00 (2013.01); C07B 33/00 (2013.01); C07B 41/02 (2013.01); C07B 63/02 (2013.01); B01J 2219/00033 (2013.01); B01J 2219/00051 (2013.01); B01J 2219/00162 (2013.01);
Abstract

A purified acid composition including 2,5-furandicarboxylic acid is prepared in a process, including oxidizing a feedstock containing 5-alkoxymethylfurfural to an oxidation product including 2,5-furandicarboxylic acid (FDCA) and 2-formyl-furan-5-carboxylic acid (FFCA), and esters of FDCA and, optionally, esters of FFCA; hydrolyzing the at least part of the oxidation product in the presence of water, thereby hydrolyzing at least esters of FDCA and, optionally, esters of FFCA to obtain an aqueous solution of an acid composition including FDCA, FFCA and ester of FDCA in an amount below the amount of ester of FDCA in the solution of the oxidation product; contacting at least part of the solution of the acid composition with hydrogen in the presence of a hydrogenation catalyst to hydrogenate FFCA to hydrogenation products, yielding a hydrogenated solution; and separating at least a portion of the FDCA from at least part of the hydrogenated solution by crystallization.


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