The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 05, 2019

Filed:

Dec. 18, 2015
Applicant:

Technip E&c Limited, Milton Keynes, Buckinghamshire, GB;

Inventor:
Assignee:

TECHNIP E&C LIMITED, Milton Keynes, Buckinghamshire, GB;

Attorneys:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
B01J 27/188 (2006.01); B01J 37/02 (2006.01); B01J 23/30 (2006.01); C07C 1/24 (2006.01);
U.S. Cl.
CPC ...
B01J 27/188 (2013.01); B01J 23/30 (2013.01); B01J 37/0205 (2013.01); C07C 1/24 (2013.01); C07C 2521/08 (2013.01); C07C 2523/04 (2013.01); C07C 2523/30 (2013.01); C07C 2527/188 (2013.01);
Abstract

A process for the vapour phase chemical dehydration of ethanol in a reactor in the presence of a supported heteropolyacid catalyst, said process comprising a step of contacting the ethanol with the heteropolyacid catalyst, wherein the heteropolyacid catalyst comprises a partially neutralised silicotungstic acid salt, wherein the partially neutralised silicotungstic acid salt has from 30% to 70% of the hydrogen atoms replaced with cations selected from the group consisting of alkali metal cations, alkaline earth metal cations, transition metal cations, ammonium cations, and mixtures thereof; but with the proviso that the alkali metal cation is not lithium; and wherein, after attaining steady-state performance of the catalyst, said process is operated continuously with the same supported heteropolyacid catalyst for at least 150 hours, without any regeneration of the catalyst.


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