The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 22, 2019

Filed:

Aug. 02, 2017
Applicant:

Shell Oil Company, Houston, TX (US);

Inventors:

Evert Van Der Heide, Amsterdam, NL;

Pieter Huizenga, Amsterdam, NL;

Dionysius Jacobus Maria De Vlieger, Amsterdam, NL;

Assignee:

SHELL OIL COMPANY, Houston, TX (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 29/00 (2006.01); C07C 31/00 (2006.01); B01J 23/00 (2006.01); C07C 29/132 (2006.01); C07C 29/76 (2006.01); B01J 23/04 (2006.01); B01J 23/30 (2006.01); C07C 31/20 (2006.01);
U.S. Cl.
CPC ...
C07C 29/132 (2013.01); B01J 23/04 (2013.01); B01J 23/30 (2013.01); C07C 29/76 (2013.01); C07C 31/202 (2013.01); C07C 31/205 (2013.01);
Abstract

The invention provides a process for the preparation of glycols from a saccharide-containing feedstock in a reactor system, said process comprising: i) providing a first feed stream comprising said saccharide-containing feedstock in a first solvent at a N temperature of no more than 160° C.; ii) providing a second feed stream comprising a tungsten-based retro-aldol catalytic species and an alkali metal containing species in a second solvent at a temperature in the range of from 150 to 250° C.; iii) combining the first feed stream and the second feed stream, before they are provided to the reactor system, to form a combined feed stream; iv) providing the combined feed stream to the reactor system and operating the reactor at a temperature in the range of from 150° C. to 250° C.; and v) also contacting the combined feed stream with a hydrogenation catalytic species in the presence of hydrogen, wherein the molar ratio of alkali metal:tungsten in the combined feed stream is in the range of from 0.55 to 6.


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