The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 24, 2019

Filed:

Feb. 15, 2017
Applicants:

Saudi Arabian Oil Company, Dhahran, SA;

Korea Advanced Institute of Science and Technology, Daejeon, KR;

Inventors:

Yuguo Wang, Dhahran, SA;

Cemal Ercan, Dhahran, SA;

Rashid M. Othman, Khobar, SA;

Minkee Choi, Daejeon, KR;

Seokin Choi, Daejeon, KR;

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C01B 31/08 (2006.01); B01J 20/20 (2006.01); B01J 20/28 (2006.01); B01J 20/32 (2006.01); B01J 20/30 (2006.01); B01J 19/24 (2006.01); B01J 3/00 (2006.01); C01B 32/05 (2017.01); C01B 32/306 (2017.01); C10L 3/06 (2006.01);
U.S. Cl.
CPC ...
B01J 20/20 (2013.01); B01J 3/008 (2013.01); B01J 19/2415 (2013.01); B01J 20/28045 (2013.01); B01J 20/28066 (2013.01); B01J 20/28073 (2013.01); B01J 20/28076 (2013.01); B01J 20/3057 (2013.01); B01J 20/3078 (2013.01); B01J 20/3204 (2013.01); B01J 20/324 (2013.01); B01J 20/3214 (2013.01); C01B 32/05 (2017.08); C01B 32/306 (2017.08); C10L 3/06 (2013.01); B01D 2253/102 (2013.01); B01D 2257/7025 (2013.01); B01D 2259/4525 (2013.01); B01J 2219/0011 (2013.01); B01J 2219/00094 (2013.01); B01J 2219/00105 (2013.01); B01J 2219/00135 (2013.01); B01J 2219/00157 (2013.01); B01J 2219/00159 (2013.01); C01P 2006/12 (2013.01); C01P 2006/14 (2013.01); Y02C 20/20 (2013.01); Y02P 20/134 (2015.11);
Abstract

Embodiments provide a methane microporous carbon adsorbent including a thermally-treated CVD carbon having a shape in the form of a negative replica of a crystalline zeolite has a BET specific surface area, a micropore volume, a micropore to mesopore volume ratio, a stored methane value and a methane delivered value and a sequential carbon synthesis method for forming the methane microporous carbon adsorbent. Introducing an organic precursor gas for a chemical vapor deposition (CVD) period to a crystalline zeolite that is maintained at a CVD temperature forms the carbon-zeolite composite. Introducing a non-reactive gas for a thermal treatment period to the carbon-zeolite composite maintained at a thermal treatment temperature forms the thermally-treated carbon-zeolite composite. Introducing an aqueous strong mineral acid mixture to the thermally-treated carbon-zeolite composite forms the methane microporous carbon adsorbent. The crystalline zeolite includes tri-ethanolamine (TEA) and has a shape that is orthogonal with a mid-edge length in a range of 8 μm to 20 μm.


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