The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Patent No.:

US 10414701 B1

PDF
Full Text
Expired
Date of Patent:
Sep. 17, 2019

Filed:

Dec. 13, 2017
Applicant:

Exxonmobil Research and Engineering Company, Annandale, NJ (US);

Inventors:

Jihad M. Dakka, Whitehouse Station, NJ (US);

Guang Cao, Princeton, NJ (US);

Patrick L. Hanks, Bridgewater, NJ (US);

James R. Bielenberg, Lebanon, NJ (US);

Cynthia F. Omilian, Whitehouse Station, NJ (US);

Jessica M. Wittmann, Easton, PA (US);

Assignee:
Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C07C 2/86 (2006.01); C07C 2/02 (2006.01); C07C 1/24 (2006.01); C07C 2/12 (2006.01); C07C 2/62 (2006.01); C07C 31/12 (2006.01); C07C 31/125 (2006.01); C07C 29/50 (2006.01); B01J 29/70 (2006.01); C07C 5/02 (2006.01); C07C 29/132 (2006.01); C07C 5/03 (2006.01); C07C 5/27 (2006.01); C07C 407/00 (2006.01); C10G 45/58 (2006.01); C10G 50/00 (2006.01); C10G 69/12 (2006.01); C10G 3/00 (2006.01); B01J 29/80 (2006.01); B01J 29/50 (2006.01);
U.S. Cl.
CPC ...
C07C 2/864 (2013.01); B01J 29/7038 (2013.01); B01J 29/80 (2013.01); C07C 1/24 (2013.01); C07C 2/12 (2013.01); C07C 2/62 (2013.01); C07C 5/02 (2013.01); C07C 5/03 (2013.01); C07C 5/2702 (2013.01); C07C 29/132 (2013.01); C07C 29/50 (2013.01); C07C 31/12 (2013.01); C07C 31/125 (2013.01); C07C 407/00 (2013.01); C10G 3/49 (2013.01); C10G 45/58 (2013.01); C10G 50/00 (2013.01); C10G 69/126 (2013.01); B01J 29/50 (2013.01); C07C 2523/28 (2013.01); C07C 2523/34 (2013.01); C07C 2523/889 (2013.01); C07C 2529/70 (2013.01); C10G 2300/104 (2013.01); C10G 2300/1044 (2013.01); C10G 2300/1081 (2013.01); C10G 2300/305 (2013.01); C10G 2400/02 (2013.01);
Abstract

Systems and methods are provided for forming alkylate from an isoparaffin-containing feed. Olefins for the alkylation reaction can be generated from a portion of the isoparaffin-containing feed. This can be achieved, for example, by using selective oxidation to convert a portion of isoparaffins into alcohol, such as conversion of isobutane to t-butyl alcohol. The alcohol can then be converted to an alkene, such as conversion of t-butyl alcohol to isobutene, in the alkylation reaction environment in the presence of a solid acid catalyst. The solid acid catalyst can then facilitate alkylation of isoparaffin using the in-situ formed alkenes. A catalyst having an MWW framework is an example of a suitable solid acid catalyst.


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