The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 20, 2019

Filed:

Dec. 28, 2015
Applicant:

Exxonmobil Chemical Patents Inc., Baytown, TX (US);

Inventors:

Jo Ann M. Canich, Houston, TX (US);

Rainer Kolb, Kingwood, TX (US);

Periagaram S. Ravishankar, Kingwood, TX (US);

Phillip T. Matsunaga, Houston, TX (US);

Peijun Jiang, League City, TX (US);

Rhutesh K. Shah, Katy, TX (US);

Narayanaswami Dharmarajan, Houston, TX (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F 210/16 (2006.01); C08L 23/16 (2006.01); C08F 4/76 (2006.01); C08F 210/06 (2006.01); C08F 210/18 (2006.01); C08F 4/659 (2006.01);
U.S. Cl.
CPC ...
C08L 23/16 (2013.01); C08F 4/76 (2013.01); C08F 210/06 (2013.01); C08F 210/16 (2013.01); C08F 210/18 (2013.01); C08F 4/65908 (2013.01); C08F 2500/09 (2013.01); C08F 2500/17 (2013.01); C08L 2205/02 (2013.01); C08L 2205/025 (2013.01); C08L 2205/06 (2013.01); C08L 2207/07 (2013.01); C08L 2312/04 (2013.01); C08L 2314/06 (2013.01);
Abstract

Provided herein are metallocene-catalyzed polymer compositions that exhibit advantageous rheological properties, at least some of which are consistent with long-chain branching, as well as polymerization processes suitable for forming such polymer compositions. The polymer compositions may have both LCB index measured at 125° C. of less than 5; and phase angle δ at complex shear modulus G*=100,000 Pa of less than about 54.5°, as determined at 125° C. The polymer compositions of particular embodiments are reactor blends, preferably of ethylene copolymers (e.g., ethylene-propylene (EP) copolymers and/or ethylene-propylene-diene (EPDM) terpolymers). The reactor blend may include first and second copolymer components, which may differ in monomer content and weight-average molecular weight (Mw).


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