The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 06, 2019

Filed:

Jun. 08, 2015
Applicant:

3m Innovative Properties Company, St. Paul, MN (US);

Inventors:

Joon Chatterjee, Bloomington, MN (US);

Jitendra Rathore, Woodbury, MN (US);

Babu N. Gaddam, Woodbury, MN (US);

Jayshree Seth, Woodbury, MN (US);

Corinne E. Lipscomb, St. Paul, MN (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C09J 4/06 (2006.01); C09J 11/04 (2006.01); C08F 220/10 (2006.01); C08G 77/442 (2006.01); C09J 133/06 (2006.01); C09J 183/10 (2006.01); C08K 5/101 (2006.01);
U.S. Cl.
CPC ...
C09J 4/06 (2013.01); C08F 220/10 (2013.01); C08K 5/101 (2013.01); C09J 11/04 (2013.01); C09J 133/06 (2013.01); C09J 183/10 (2013.01); C08G 77/442 (2013.01); C09J 2201/606 (2013.01); C09J 2205/106 (2013.01); C09J 2433/00 (2013.01); C09J 2483/00 (2013.01);
Abstract

Pressure sensitive adhesive compositions are described comprising at least one low Tg ethylenically unsaturated monomer, and at least one silsesquioxane polymer crosslinker comprising a plurality of ethylenically unsaturated groups. The low Tg ethylenically unsaturated monomer typically has a Tg no greater than 10° C. In some embodiments, the composition comprises at least 50, 55, 60, 65, or 70 wt-% of low Tg ethylenically unsaturated monomer. The low Tg ethylenically unsaturated monomer is typically an alkyl (meth)acrylate comprising 4 to 20 carbon atoms. In another embodiment, an adhesive composition is described comprising a syrup. The syrup comprising i) a free-radically polymerizable solvent monomer; ii) a solute (meth)acrylic polymer comprising polymerized units derived from one or more alkyl (meth)acrylate monomers, and iii) at least one silsesquioxane polymer crosslinker comprising a plurality of ethylenically unsaturated groups. The free-radically polymerizable solvent monomer, polymerized units of the solute (meth)acrylic polymer, or a combination thereof comprise a low Tg ethylenically unsaturated monomer. Also described are pressure sensitive adhesive articles and method of preparing adhesive articles.


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