The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 30, 2019

Filed:

Jul. 15, 2014
Applicant:

Solvay SA, Brussels, BE;

Inventors:

Julio A. Abusleme, Saronno, IT;

Giambattista Besana, Mariano Comense, IT;

Mattia Bassi, Milan, IT;

Christine Hamon, Arese, IT;

Chiara Gualandi, Comune di Molinel, IT;

Maria Letizia Focarete, Bologna, IT;

Andrea Zucchelli, Crevalcore, IT;

Assignee:

SOLVAY SA, Brussels, BE;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
D01F 6/32 (2006.01); B01D 71/32 (2006.01); C08F 214/18 (2006.01); D04H 1/4318 (2012.01); D04H 1/728 (2012.01); D01D 5/00 (2006.01); D01F 1/10 (2006.01); D01F 6/48 (2006.01); B01D 67/00 (2006.01); B01D 71/76 (2006.01); D02J 1/00 (2006.01); H01M 10/0525 (2010.01); H01M 2/16 (2006.01); H01M 10/052 (2010.01);
U.S. Cl.
CPC ...
D01F 6/32 (2013.01); B01D 67/0079 (2013.01); B01D 71/32 (2013.01); B01D 71/76 (2013.01); C08F 214/18 (2013.01); D01D 5/003 (2013.01); D01D 5/0038 (2013.01); D01F 1/10 (2013.01); D01F 6/48 (2013.01); D02J 1/00 (2013.01); D04H 1/4318 (2013.01); D04H 1/728 (2013.01); H01M 10/0525 (2013.01); D10B 2321/042 (2013.01); D10B 2321/08 (2013.01); D10B 2401/06 (2013.01); D10B 2401/061 (2013.01); D10B 2401/16 (2013.01); D10B 2505/00 (2013.01); D10B 2505/04 (2013.01); H01M 2/162 (2013.01); H01M 2/1686 (2013.01); H01M 10/052 (2013.01);
Abstract

The present invention pertains to a process for manufacturing one or more fluoropolymer fibers, said process comprising the following steps: (i) providing a liquid composition [composition (C1)] comprising: —at least one fluoropolymer comprising at least one hydroxyl end group [polymer (F)L and —a liquid medium comprising at least one organic solvent [solvent (S)]; (ii) contacting the composition (C1) provided in step (i) with at least one metal compound [compound (M)] of formula (I) here below: XAY(I) wherein X is a hydrocarbon group, optionally comprising one or more functional groups, m is an integer from 1 to 4, A is a metal selected from the group consisting of Si, Ti and Zr, and Y is a hydrolysable group selected from the group consisting of an alkoxy group, an acyloxy group and a hydroxyl group, thereby providing a liquid composition [composition (C2)]; (iii) submitting to at least partial hydrolysis and/or polycondensation the composition (C2) provided in step (ii) thereby providing a liquid composition [composition (C3)] comprising at least one fluoropolymer hybrid organic/inorganic composite; (iv) processing the composition (C3) provided in step (iii) by electrospinning thereby providing one or more fluoropolymer fibers; (v) drying the fluoropolymer fiber(s) provided in step (iv); and (vi) optionally, submitting to compression the fluoropolymer fiber(s) provided in step (v) at a temperature comprised between 50° C. and 300° C. The invention also pertains to a process for the manufacture of said fluoropolymer fiber(s) and to uses of said fluoropolymer fiber(s) in various applications.


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