The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 25, 2019

Filed:

Jan. 16, 2014
Applicant:

Asemblon Inc., Woodinville, WA (US);

Inventors:

Esmaeel Naeemi, Woodinville, WA (US);

David G. O'Connor, Woodinville, WA (US);

Maitham Naeemi, Woodnville, WA (US);

Assignee:

Other;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 19/18 (2006.01); B01J 8/00 (2006.01); C01B 3/22 (2006.01); C07C 253/00 (2006.01); B01J 19/24 (2006.01); B01J 8/02 (2006.01); C01B 3/50 (2006.01);
U.S. Cl.
CPC ...
B01J 19/1893 (2013.01); B01J 8/009 (2013.01); B01J 8/0214 (2013.01); B01J 8/0221 (2013.01); B01J 19/249 (2013.01); C01B 3/22 (2013.01); C01B 3/501 (2013.01); C07C 253/00 (2013.01); B01J 2208/00053 (2013.01); B01J 2208/00407 (2013.01); B01J 2208/00415 (2013.01); C01B 2203/0277 (2013.01); C01B 2203/041 (2013.01); C01B 2203/048 (2013.01); C01B 2203/066 (2013.01); C01B 2203/107 (2013.01); C01B 2203/1047 (2013.01); C01B 2203/1052 (2013.01); C01B 2203/1058 (2013.01); C01B 2203/1064 (2013.01);
Abstract

The current disclosure is directed to a hydrogen-storage system that employs catalytic dehydrogenation of low-molecular-weight amines in a hydrogen reactor. The hydrogen-storage system comprises aliphatic amines and di-amines as organic carriers that store hydrogen covalently, a hydrogen reactor that releases and separates hydrogen gas from the carrier, and metal or metal-oxide catalysts that promote a dehydrogenation reaction to release hydrogen. In certain implementations, a metal or metal-oxide catalyst may be carried on high-surface-area support materials, such as gamma-alumina and metal-organic-framework materials, to enhance catalytic properties. The hydrogen reactor may be a packed-bed reactor, a monolith reactor, or a flow-through hydrogen-membrane reactor. In one implementation, the flow-through hydrogen-membrane reactor comprises an inlet through which the organic hydrogen carrier flows into the reactor, a hydrogen-separation membrane selectively permeable to hydrogen, a recirulation outlet for removing unspent organic carrier, and a hydrogen outlet for releasing hydrogen and reaction byproducts. The spent organic carrier are collected and hydrogenated to regenerate the original fuel.


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