The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 11, 2019

Filed:

Dec. 07, 2016
Applicants:

Annikki Gmbh, Raaba-Grambach, AT;

Microinnova Engineering Gmbh, Allerheiligen b. Wildon, AT;

Inventors:

Gunter Tekautz, Graz, AT;

Dirk Kirschneck, Albersdorf-Prebuch, AT;

Walter Linhart, Graz, AT;

Assignees:

ANNIKKI GMBH, Raaba-Grambach, AT;

NOVOLANA GMBH, Tobelbad, AT;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07D 307/68 (2006.01);
U.S. Cl.
CPC ...
C07D 307/68 (2013.01);
Abstract

The present invention relates to a process for the production of 2,5-furandicarboxylic acid (FDCA) via oxidation of 5-hydroxymethyl-2-furfural (HMF), said HMF being present in a solution in a high-boiling polar solvent and water. The process is characterized by the combination of —a first oxidation step wherein the HMF is at least partly oxidized in said solution to yield a first reaction mixture comprising at least one monoacid selected from the group consisting of -hydroxymethylfuran-2-carboxylic acid (HMFA), 5-formylfuran-2-carboxylic acid (FFCA) and, optionally, FDCA —an extraction step after the first oxidation step wherein said high-boiling polar solvent is extracted from said first reaction mixture by means of an extraction solvent, wherein said at least one monoacid remains in an aqueous phase, —a second oxidation step wherein said at least one monoacid is oxidized to FDCA.


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