The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 11, 2019

Filed:

Dec. 08, 2015
Applicant:

Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, CN;

Inventors:

Youming Ni, Dalian, CN;

Wenliang Zhu, Dalian, CN;

Yong Liu, Dalian, CN;

Hongchao Liu, Dalian, CN;

Lei Shi, Dalian, CN;

Zhongmin Liu, Dalian, CN;

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C07C 29/10 (2006.01); C07C 31/20 (2006.01); B01J 29/70 (2006.01); B01J 39/05 (2017.01); B01J 29/08 (2006.01); B01J 29/18 (2006.01); B01J 29/40 (2006.01); B01J 29/65 (2006.01); B01J 31/02 (2006.01);
U.S. Cl.
CPC ...
C07C 29/10 (2013.01); B01J 29/088 (2013.01); B01J 29/185 (2013.01); B01J 29/405 (2013.01); B01J 29/655 (2013.01); B01J 29/70 (2013.01); B01J 29/7057 (2013.01); B01J 29/7088 (2013.01); B01J 31/0227 (2013.01); B01J 39/05 (2017.01); C07C 31/202 (2013.01); C07C 2529/08 (2013.01); C07C 2529/18 (2013.01); C07C 2529/40 (2013.01); C07C 2529/65 (2013.01); C07C 2529/70 (2013.01); C07C 2531/025 (2013.01); Y02P 20/52 (2015.11);
Abstract

This invention provides a method for preparing ethylene glycol by hydrolyzing ethylene glycol monomethyl ether. The method comprises passing a fresh raw material containing ethylene glycol monomethyl ether and water through a reaction zone loaded with a solid acid catalyst to react under the following conditions; separating the reacted mixture via a separation system to obtain a target product of ethylene glycol, by-products containing methanol, dimethyl ether and ethylene glycol-based derivatives, and an unreacted raw material containing ethylene glycol monomethyl ether and water; passing the target product of ethylene glycol into a product collection system; and passing methyl alcohol and dimethyl ether in the by-products into a by-product collection system; and after being mixed with the fresh raw materials containing ethylene glycol monomethyl ether and water, the ethylene glycol-based derivatives in the by-products and the unreacted raw material containing ethylene glycol monomethyl ether and water being recycled into the reaction zone, to realize the preparation of ethylene glycol by hydrolyzing ethylene glycol monomethyl ether. This invention provides a new process to realize the preparation of ethylene glycol by hydrolyzing ethylene glycol monomethyl ether. And in the method, the catalyst has long life and good stability.


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