The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 04, 2019

Filed:

Apr. 08, 2016
Applicant:

Northwestern University, Evanston, IL (US);

Inventors:

Daniel Morgan Wells, Charlotte, NC (US);

Paul L. Frattini, Los Altos, CA (US);

Keith Paul Fruzzetti, San Jose, CA (US);

Omar Farha, Glenview, IL (US);

Joseph T. Hupp, Northfield, IL (US);

Ashlee J. Howarth, Evanston, IL (US);

Michael J. Katz, St. John's, CA;

Assignee:

Northwestern University, Evanston, IL (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C02F 1/28 (2006.01); B01J 20/22 (2006.01); C02F 1/42 (2006.01); C02F 103/18 (2006.01); C02F 101/10 (2006.01);
U.S. Cl.
CPC ...
C02F 1/285 (2013.01); B01J 20/226 (2013.01); C02F 2001/422 (2013.01); C02F 2101/106 (2013.01); C02F 2103/18 (2013.01);
Abstract

The present invention provides a metal-organic framework (MOF) for use in removing particular chemical species or compounds from a liquid. In particular, the present invention provides an MOF having a molecular formula of Zr(μ-O)(μOH)(OH)(HO)(TBAPy), wherein TBAPy is 1,3,6,8-tetrakis (p-benzoic-acid)pyrene, (known as NU-1000) for use in complexing selenate or selenite from a liquid or liquid stream. Further, the selenium based oxy-anions are removed to concentrations below that specified for wastewater discharge by the U.S. Environmental Protection Agency for flue gas desulfurization operations in the fossil fueled electric power generation industry. Such water treatment results are achieved even in the presence of competing sulfate anion challenges and at elevated temperatures comparable to condensate cooling water.


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