The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 28, 2019

Filed:

Jan. 30, 2015
Applicant:

International Business Machines Corporation, Armonk, NY (US);

Inventors:

Nestor A. Bojarczuk, Poughkeepsie, NY (US);

Talia S. Gershon, White Plains, NY (US);

Supratik Guha, Chappaqua, NY (US);

Marinus Hopstaken, Carmel, NY (US);

Byungha Shin, Daejeon, KR;

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C23C 14/00 (2006.01); H01L 31/032 (2006.01); C23C 14/06 (2006.01);
U.S. Cl.
CPC ...
H01L 31/0326 (2013.01); C23C 14/0026 (2013.01); C23C 14/0623 (2013.01); Y02E 10/50 (2013.01);
Abstract

A method and apparatus for manufacturing a nitrogen-doped CZTSSe layer for a solar cell is disclosed. A substrate is mounted in a vacuum chamber. A plurality of effusion cells are placed within the vacuum chamber in order to evaporate copper, zinc, tin, sulfur, and/or selenium to form elemental vapors in a region proximate the substrate. An RF-based nitrogen source delivers a nitrogen plasma in the region proximal to the substrate. The elemental vapors and the nitrogen plasma form a gas mixture in the region near the substrate, which then react at the substrate to form a CZTSSe absorber layer for a solar cell.


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