The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 28, 2019

Filed:

Jul. 25, 2012
Applicants:

Nikolai Nesterenko, Nivelles, BE;

Delphine Minoux, Nivelles, BE;

Cindy Adam, Wierde, BE;

Jean-pierre Dath, Beloeil, BE;

Inventors:

Nikolai Nesterenko, Nivelles, BE;

Delphine Minoux, Nivelles, BE;

Cindy Adam, Wierde, BE;

Jean-Pierre Dath, Beloeil, BE;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 29/85 (2006.01); C07C 4/06 (2006.01); C07C 2/86 (2006.01); C07C 2/08 (2006.01); C07C 1/22 (2006.01); B01J 37/10 (2006.01); B01J 37/28 (2006.01); B01J 29/40 (2006.01); C07C 1/20 (2006.01); C07C 1/24 (2006.01); C07C 2/66 (2006.01); C10G 29/20 (2006.01); C10G 29/22 (2006.01); C10G 3/00 (2006.01); B01J 37/00 (2006.01); B01J 29/65 (2006.01); B01J 29/70 (2006.01);
U.S. Cl.
CPC ...
B01J 29/85 (2013.01); B01J 29/40 (2013.01); B01J 37/0009 (2013.01); B01J 37/10 (2013.01); B01J 37/28 (2013.01); C07C 1/20 (2013.01); C07C 1/22 (2013.01); C07C 1/24 (2013.01); C07C 2/08 (2013.01); C07C 2/66 (2013.01); C07C 2/864 (2013.01); C07C 4/06 (2013.01); C10G 3/49 (2013.01); C10G 29/205 (2013.01); C10G 29/22 (2013.01); B01J 29/65 (2013.01); B01J 29/7023 (2013.01); B01J 29/7026 (2013.01); B01J 29/7038 (2013.01); B01J 29/7042 (2013.01); B01J 29/7046 (2013.01); B01J 2229/36 (2013.01); B01J 2229/37 (2013.01); B01J 2229/42 (2013.01); C07C 2521/08 (2013.01); C07C 2527/14 (2013.01); C07C 2529/40 (2013.01); C07C 2529/65 (2013.01); Y02P 20/52 (2015.11); Y02P 30/42 (2015.11);
Abstract

A method to make a phosphorus modified zeolite can include providing a zeolite including at least one ten member ring in the structure, steaming the zeolite, mixing the zeolite with one or more binders and shaping additives, and then shaping the mixture. The method can include making a ion-exchange. The shaped mixture can be steamed. Phosphorous can be introduced on the catalyst to introduce at least 0.1 wt % of phosphorus, such as be dry impregnation or chemical vapor deposition. A metal, such as calcium, can be introduced. The catalyst can be washed, calcinated, and then steamed. The steaming severity (X) can be at least about 2. The catalyst can be steamed at a temperature above 625° C., such as a temperature ranging from 700 to 800° C. The catalyst can be used in alcohol dehydration, olefin cracking, MTO processes, and alkylation of aromatics by alcohols with olefins and/or alcohols.


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