The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 21, 2019

Filed:

Dec. 07, 2016
Applicant:

Shell Oil Company, Houston, TX (US);

Inventors:

Leslie Andrew Chewter, Amsterdam, NL;

Jean Paul Andre Marie Joseph Ghislain Lange, Amsterdam, NL;

Duraisamy Muthusamy, Houston, TX (US);

Timothy Michael Nisbet, Amsterdam, NL;

Evert Van Der Heide, Amsterdam, NL;

Pieter Huizenga, Amsterdam, NL;

Assignee:

SHELL OIL COMPANY, Houston, TX (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 29/60 (2006.01); C07C 31/00 (2006.01); B01J 19/00 (2006.01); C07C 29/132 (2006.01); B01J 8/20 (2006.01); B01J 8/22 (2006.01); B01J 10/00 (2006.01); B01J 16/00 (2006.01); B01J 19/18 (2006.01); B01J 19/24 (2006.01); C07C 31/20 (2006.01);
U.S. Cl.
CPC ...
C07C 29/132 (2013.01); B01J 8/20 (2013.01); B01J 8/22 (2013.01); B01J 10/007 (2013.01); B01J 16/005 (2013.01); B01J 19/1881 (2013.01); B01J 19/2465 (2013.01); C07C 29/60 (2013.01); C07C 31/202 (2013.01); C07C 31/205 (2013.01); B01J 2208/00283 (2013.01); B01J 2219/0011 (2013.01); C07C 2521/06 (2013.01); C07C 2523/22 (2013.01); C07C 2523/26 (2013.01); C07C 2523/28 (2013.01); C07C 2523/30 (2013.01); Y02P 20/582 (2015.11);
Abstract

The invention provides a continuous process for the preparation of ethylene glycol and 1, 2-propylene glycol from starting material comprising one or more saccharides, said process being carried out in a reactor system comprising a reactor vessel equipped with an external recycle loop and said process comprising the steps of: i) providing the starting material in a solvent, via an inlet, to the external recycle loop and contacting it therein with a retro-aldol catalyst composition to provide an intermediate stream; ii) then contacting said intermediate stream with hydrogen in the presence of a hydrogenation catalyst composition in the reactor vessel; iii) withdrawing a product stream comprising glycols from the reactor vessel; iv) providing a portion of said product stream, via an outlet, for separation and purification of the glycols contained therein; and v) recycling the remainder of said product stream via the external recycle loop.


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