The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 21, 2019

Filed:

Jan. 13, 2016
Applicant:

Avantium Knowledge Centre B.v., Amsterdam, NL;

Inventors:

Jan Cornelis Van Der Waal, Amsterdam, NL;

Gerardus Johannes Maria Gruter, Amsterdam, NL;

Erik-Jan Ras, Amsterdam, NL;

Assignee:
Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
B01J 23/46 (2006.01); B01J 23/62 (2006.01); B01J 23/89 (2006.01); B01J 37/02 (2006.01); B01J 37/18 (2006.01); C07C 29/60 (2006.01); C07C 29/82 (2006.01); C07C 31/20 (2006.01); C07C 29/132 (2006.01);
U.S. Cl.
CPC ...
C07C 29/132 (2013.01); B01J 23/462 (2013.01); B01J 23/468 (2013.01); B01J 23/626 (2013.01); B01J 23/892 (2013.01); B01J 23/8926 (2013.01); B01J 37/0201 (2013.01); B01J 37/0236 (2013.01); B01J 37/18 (2013.01); C07C 29/60 (2013.01); C07C 29/82 (2013.01); Y02P 20/52 (2015.11);
Abstract

Ethylene glycol is prepared from a carbohydrate source in a process, wherein hydrogen, the carbohydrate source, a liquid diluent and a catalyst system are introduced as reactants into a reaction zone; wherein the catalyst system comprises a tungsten compound and ruthenium as hydrogenolysis metal and further at least one promoter metal, selected from transition and post-transition metals; wherein the carbohydrate source is reacted with hydrogen in the presence of the catalyst system to yield a product mixture comprising ethylene glycol and butylene glycol. Butylene glycol may selectively be removed from the product mixture by azeotropic distillation using an entraining agent.


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