The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 07, 2019

Filed:

Jun. 10, 2015
Applicant:

Rohm and Haas Company, Philadelphia, PA (US);

Inventors:

James C. Bohling, Lansdale, PA (US);

Arnold S. Brownell, Lansdale, PA (US);

Michael D. Kelly, North Wales, PA (US);

Assignee:

Rohm and Haas Company, Collegeville, PA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F 2/00 (2006.01); C08F 2/24 (2006.01); C08F 2/26 (2006.01); D04H 1/64 (2012.01); C08F 30/02 (2006.01); C08F 36/20 (2006.01); C08L 43/02 (2006.01); C08L 61/06 (2006.01); C08L 61/24 (2006.01); D04H 1/587 (2012.01); C08F 212/08 (2006.01); C08F 212/14 (2006.01); C08F 220/06 (2006.01); C08F 220/18 (2006.01); C08F 230/08 (2006.01); C08F 290/00 (2006.01); C09J 161/24 (2006.01); D04H 1/4218 (2012.01); D06M 15/432 (2006.01);
U.S. Cl.
CPC ...
C08L 61/24 (2013.01); C08F 2/001 (2013.01); C08F 2/24 (2013.01); C08F 2/26 (2013.01); C08F 30/02 (2013.01); C08F 36/20 (2013.01); C08F 220/18 (2013.01); C08F 290/00 (2013.01); C08L 43/02 (2013.01); C08L 61/06 (2013.01); C09J 161/24 (2013.01); D04H 1/4218 (2013.01); D04H 1/587 (2013.01); D04H 1/64 (2013.01); D06M 15/432 (2013.01); C08F 212/08 (2013.01); C08F 212/14 (2013.01); C08F 220/06 (2013.01); C08F 2220/1825 (2013.01); C08F 2230/085 (2013.01); C08L 2201/52 (2013.01); C08L 2201/54 (2013.01); D10B 2101/06 (2013.01);
Abstract

The present invention provides polymer modified aqueous urea formaldehyde resin (UF resin) binder compositions useful in making a treated glass mat, e.g., for roofing shingles, wherein the polymer modifier is an multistage aqueous emulsion acorn copolymer comprising one protuberant polymer stage containing phosphorous acid groups and one or more other polymer stage comprising an addition copolymer incompatible with the protuberant polymer stage, wherein the multistage aqueous emulsion copolymer has a measured Tg of from −60 to 25° C., or, preferably from −30 to 12° C. and, further wherein the weight ratio of the total of monomers used to make the one or more other polymer stage to the total amount of monomers used to make the protuberant polymer stage ranges from 3:1 to 50:1, or, preferably, from 3:1 to 30:1 or, more preferably, from 3:1 to 20:1, or, even more preferably, from 8:1 to 12:1.


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